Hi, when you did not save anything then of course you will not get different results from before, but maybe you did some changes and saved them, before?
A singular matrix (the message refers to the technosphere matrix) cannot be solved, simply speaking; you get this e.g. when you have rows or lines in the matrix that are linearly dependent from each other, so e.g. just a constant factor different. This happens e.g. if you have two lines that are completely 0. This is the inventory calculation, so using a different impact method does not help.
You can check the matrix by enabling matrix image export in openLCA (go to preferences) and then you can, for a product system, export the matrices from the calculation. Check the A matrix.
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Hope this helps, Andreas