I think you need to provide some more details on this to get some answers.
You want to compare the impact analysis of individual processes or you want to compare the process-level contributions within a system?
I'm not sure what's going on in the second bullet. The impact categories should reflect whatever impact method you select when you calculate a product system. The other thing you may be running into is that impact assessments from the "Impact analysis" tab of a process not matching the impacts when they're calculated within a product system. The most likely culprit here are duplicate flows. The "Impact analysis" tab will only calculate the impacts from the first instance of the flow - so if there are two methane flows (with the same UUID), it will only calculate using one of those.
I think you need to tell us which normalization method you've used, and someone may be able to provide the units. As an example for TRACI, I believe the normalization units are per 1,000 people or something like that - as in, the combined environmental impacts of a product system are equivalent to the combined US impacts are for every 1,000 people.