So you export the normal impact analysis results to excel (or the entire calculation results) not the contribution tree, right? Meaning that "excel data" in your question is also openLCA result (and maybe not "data"), just as contribution tree results.
The point is that the contribution tree shows individual branches / pathways of supply with their impacts, while the impact analysis results show the aggregated result, over all branches. In LCA systems, supply chains are used often more than once, also due to loops, and thus the result per supply chain is different, and often lower, than the overall result. I hope it is clear now?